介孔材料化学改性研究进展

综述了介孔材料化学改性目的，改性原理以及改性方法。介孔材料的化学改性包括对材料骨架的修饰以及对孔道表面的功能化，介孔材料表面自由硅醇键、双羟基硅醇踺是化学改性的基础，利用疏水性物质改性可以提高材料的水热稳定性，引入催化活性组分可以提高催化性能，利用具有特定官能团的硅烷偶连剂改性，则能够实现特殊的目的。详述了化学改性方法，包括元素取代法、共价键移植法和有机硅烷偶连法。元素取代法是对分子筛骨架结构的修饰，共价键移植法是一种不引起孔道结构破坏且非常有效的骨架修饰方法，对介孔材料表面进行有机硅烷偶连剂法修饰改性主要有两种途径：即共沉淀法和后移植法。     

Soil Apparent Electrical Conductivity (EC<Subscript>a</Subscript>) as a Means of Monitoring Changesin Soil Inorganic N on Heterogeneous Morainic Soils in SE Norway During Two Growing Seasons

An efficient method to monitor changes in soil inorganic N content during crop growth would be a useful means to guide N fertilization to ensure high yields and low N losses to the environment. In this study, soil apparent electrical conductivity (EC_a) measured by the widely used conductivity meter EM38 was tested as an indirect measurement of available N in spring barley during two cropping seasons at two sites with morainic loam in SE Norway. The experiment was constructed to maximize soil variation. In spite of the ȁ8noiseȁ9 caused by the soil heterogeneity, concentrations of inorganic N (cN_inorg) or NO₃-N were most strongly correlated with EC_a in both years and at both locations (with one exception). The measurements of EC_a reflected well the temporal variation in inorganic N content (N_inorg), and a ranking of the treatments based on EC_a fitted very well with a ranking based on N_inorg at the first three sampling times after fertilizing. The best subset of sensor variables (i.e. variables which can be measured ȁ8on-the-goȁ9 by sensor techniques in the field) described 27–69% (average 47%) of the variation in topsoil cN_inorg. When expanding the regression models to include pH as well, the degree of explanation increased significantly. In conclusion, the method of using EC_a appears to be quite robust in terms of detecting relative differences in cN_inorg, whereas a determination of absolute levels of cN_inorg with the method is unreliable.     

流域洪水资源利用的理论框架探讨I:定量解析

自21世纪初以来,中国北方地区干旱缺水的严峻形势,催生了旨在挖掘洪水利用潜力、缓解水资源短缺矛盾的"洪水资源利用"的概念出现,并迅速成为防洪和水资源高效利用领域的研究热点。论文在梳理总结多年研究积累的基础上,从洪水资源利用概念形成与流域水量平衡方程出发,建立了流域洪水资源利用的定义和概念性模型,指出洪水资源利用的本质是风险与效益的博弈;采用极限分析理论,推理辨析与洪水资源利用潜力评价密切相关的若干概念及其定量关系;论述常见洪水资源利用方式基本原理和技术关键,进而建立涵盖洪水资源利用潜力评价、利用方式选择和风险效益评估于一体的流域洪水资源利用模式。     

Determinants of users’ continuance of social networking sites: A self-regulation perspective

Social networking sites (SNS) have transformed how individuals interact, build and maintain social relationships. We proposed a research model on the determinants of user continuance using Bagozzi's framework of self-regulation as the theoretical foundation. Following the process of appraisal → emotional reactions → coping responses, we developed the model by leveraging findings from social presence and IS continuance research. Based on survey data from Facebook users, we found that appraisal factors (pleasure, awareness, connectedness, and system quality) were strong determinants of emotional reaction (user satisfaction and sense of belonging). User satisfaction and sense of belonging together positively influenced continuance intention.     

P450酶启发的染料后修饰铁卟啉MOF光催化氧化

受细胞色素P450酶氧化代谢的启发,将染料酸性红87（Acid Red 87）后修饰到金属有机框架PCN-222(Fe)中,构筑非均相拟酶光催化剂Acid Red 87@PCN-222(Fe),拉近染料与铁卟啉中心的距离,利用光致电子转移模拟P450的电子传递链。以1-(4-甲氧基苯基)乙醇为模板底物,对光催化氧化的条件如溶剂、电子牺牲剂、氧源等进行筛选,得到优化反应条件为高碘酸钠(53.5 mg, 0.25 mmol),2,6-二甲基吡啶三氟甲磺酸盐(64.3 mg, 0.25 mmol),Acid Red 87@PCN-222(Fe)(12.0 mg, 0.00625 mmol),乙腈(2 mL),530 nm波长LED光照反应24 h。催化剂重复使用3次后仍保持活性和晶态结构。该催化体系对苄基碳氢键氧化具有良好的底物适用范围,可应用于非甾体类抗炎药匹美诺芬的区位选择性氧化，产率为48%，该体系还可将芳基硫醚类化合物氧化至相应的亚砜，体现其在精细化工制药、工业脱硫领域的应用潜质。     

塑料注射机预塑过程爬行现象的产生与控制

根据低速不稳定性的振动机理，对塑料注射机预塑过程中的爬行现象进行分析，推导出注射机液压滑台运行的“液压弹簧”模型。通过建立力学模型和系统的运动微分方程，分析主要影响因素，提出相应措施，达到注射机注射过程低速稳定的目的。     

A framework for tag-aware recommender systems

In social tagging system, a user annotates a tag to an item. The tagging information is utilized in recommendation process. In this paper, we propose a hybrid item recommendation method to mitigate limitations of existing approaches and propose a recommendation framework for social tagging systems. The proposed framework consists of tag and item recommendations. Tag recommendation helps users annotate tags and enriches the dataset of a social tagging system. Item recommendation utilizes tags to recommend relevant items to users. We investigate association rule, bigram, tag expansion, and implicit trust relationship for providing tag and item recommendations on the framework. The experimental results show that the proposed hybrid item recommendation method generates more appropriate items than existing research studies on a real-world social tagging dataset.     

传感网环境下视频传感器在线规划

针对视频传感器观测被动的问题,结合视频传感器和传感网的特点,设计了传感网环境下视频传感器在线规划框架。该框架采用面向服务的体系架构（ SOA）,包含资源层、资源服务层、规划服务层和应用层四个层,各层之间采用标准的网络通信协议进行通信。实现了视频传感器在线规划原型系统,并以视频监控签到为应用场景进行了在线规划实验。实验结果表明：该框架对于实现视频传感器主动和按需观测是可行且有效的。     

基于虚拟磁盘的携带型操作系统加密方案

针对移动硬盘的加密系统分区无法被正确辨识而导致误格式化的问题,应用文件系统过滤驱动技术,结合硬盘主引导程序及分区表机理,对现有的基于虚拟磁盘的移动硬盘加解密方案进行了改进,在加密分区包含可运行操作系统的情况下,增加了盘符自动隐藏及恢复的功能。以开源加密软件Truecrypt为例,利用安装了视窗操作系统的固态移动硬盘进行测试。结果表明,在不影响加密操作系统正常运行的同时,盘符自动隐藏及恢复功能避免了用户的误格式化操作,从而提高了移动硬盘加密系统分区的安全性和隐蔽性。     

基于SDNA-GA 优化的模糊神经网络控制

针对最新的生物DNA研究,病毒中同一DNA碱基顺序可以编码出2条或者3条不同的多肽链.在此基础上分析与模仿了重叠基因和重叠密码的机理,得到一种新的基于重叠基因编码框架,从而提高了问题求解的效率;同时,得到一种移码解读框架的DNA遗传算法(SDNA-GA)计算模型,并将其应用于一类广义隶属度型T-S模糊神经网络控制器(GTS-FNNC)的优化设计,实现了GTS-FNNC的在线学习.